degradation of gesaprim herbicide by heterogeneous photocatalysis using fe-doped tio2gesaprim除草剂的降解异构使用fe-doped二氧化钛光催化作用.pdfVIP
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degradation of gesaprim herbicide by heterogeneous photocatalysis using fe-doped tio2gesaprim除草剂的降解异构使用fe-doped二氧化钛光催化作用
International Journal of Geosciences, 2011, 2, 669-675 669
doi:10.4236/ijg.2011.24068 Published Online November 2011 (http://www.SciRP.org/journal/ijg)
Degradation of Gesaprim Herbicide by Heterogeneous
Photocatalysis Using Fe-Doped TiO2
1 1 2
Noemí Acevedo Quiroz , Dulce Jocelyn Ramos Gutierrez , Susana Silva Martínez ,
Cristina Lizama Bahena1
1
Posgrado de la Facultad de Ciencias Químicas e Ingeniería y Centro de Investigación en Ingeniería y Ciencias
Aplicadas , Universidad Autónoma del Estado de Morelos, Cuernavaca, Mexico
2Centro de Investigación en Ingeniería y Ciencias Aplicadas, Universidad Autónoma del Estado de Morelos,
Cuernavaca, Mexico
E-mail : ssilva@uaem.mx
Received June 21, 2011; revised August 7, 2011; accepted September 26, 2011
Abstract
Fe-doped TiO was prepared by the sol gel method and characterized by X-ray diffraction. All the Fe-doped
2
TiO were composed of an anatase crystal form. The activity of the Fe-doped TiO for the degradation of the
2 2
gesaprim commercial herbicide (which contains atrazine as active compound and formulating agents) was
studied by varying the iron content during UV (15 W), visible light and solar irradiations. The visible light
came from commercial saving energy lamps (13, 15 and 20 Watts). The gesaprim degradation rate depended
on the iron content in the photo catalyst. The Fe-doped TiO (0.5% by weig
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