design, synthesis and application of sio2-ratp nanoparticles for preconcentration and separation of trace copper ions a green analytical methodsio2-ratp纳米粒子的设计、合成和应用的预浓缩和分离微量铜离子绿色分析方法.pdfVIP

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design, synthesis and application of sio2-ratp nanoparticles for preconcentration and separation of trace copper ions a green analytical methodsio2-ratp纳米粒子的设计、合成和应用的预浓缩和分离微量铜离子绿色分析方法.pdf

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design, synthesis and application of sio2-ratp nanoparticles for preconcentration and separation of trace copper ions a green analytical methodsio2-ratp纳米粒子的设计、合成和应用的预浓缩和分离微量铜离子绿色分析方法

Advances in Nanoparticles, 2012, 1, 1-7 1 /10.4236/anp.2012.11001 Published Online May 2012 (http://www.SciRP.org/journal/anp) Design, Synthesis and Application of SiO -RATP 2 Nanoparticles for Preconcentration and Separation of Trace Copper Ions: A Green Analytical Method Anupreet Kaur, Usha Gupta Punjabi University, Patiala, India Email: anu_chem06,@yahoo.co.in, ushagupta_doc@ Received March 5, 2012; revised April 20, 2012; accepted May 10, 2012 ABSTRACT A new analytical method using Resacetophenone (RATP) modified SiO2 nanoparticles as solid-phase extractant has been developed for the preconcentration of trace amounts of Cu(II) in different water samples. Conditions of the analy- sis such as preconcentration factor, effect of pH, sample volume, shaking time, elution conditions and effects of inter- fering ions for the recovery of analyte were investigated. The adsorption capacity of nanometer SiO2-RATP was found to be 61.50 µmol·g–1 at optimum pH and the detection limit (3σ) was 0.36 µg·L–1 . The extractant showed rapid kinetic sorption. The adsorption equilibrium of Cu(II) on nanometer SiO2-RATP was achieved in 15 mins. Adsorbed Cu(II) was easily eluted with 5 mL of 4 M hydrochloric acid. The maximum preconcentration factor was 60. The method was applied for the determination of trace amounts of Cu(II) in various water and food samples. Keywords: Chemically Modified SiO2-Nanoparticles; Resacetophenone; Separation 1. Introduction