原创力文档determination of differential enthalpy and isotherm by adsorption calorimetry确定微分焓和等温线的吸附量热法.pdfVIP
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determination of differential enthalpy and isotherm by adsorption calorimetry确定微分焓和等温线的吸附量热法
Hindawi Publishing Corporation
Research Letters in Physical Chemistry
Volume 2008, Article ID 127328, 4 pages
doi:10.1155/2008/127328
Research Letter
Determination of Differential Enthalpy and Isotherm by
Adsorption Calorimetry
1 ´ 1 ´ 2 3 3, 4
V. Garcia-Cuello, J. C. Moreno-Pirajan, L. Giraldo-Gutierrez, K. Sapag, and G. Zgrablich
1 Research Group on Porous Solid and Calorimetry, Department of Chemistry, Faculty of Sciences,
University of the Andes, Carrera 1 No. 18 A 10 Bogota, Colombia
´
2 Department of Chemistry, Faculty of Sciences, National University of Colombia, Ciudad Universitaria,
Transversal 38 No. 40-01 Bogota, Colombia
´
3 Instituto de Fısica Aplicada (INFAP), CONICET- Universidad Nacional de San Luis, Ejercito de los Andes 950,
´ ´
San Luis D5700HHW, Argentina
4 Departamento de Engenharia Quımica, Universidade Federal do Ceara, Campus do Pici,
´ ´
Fortaleza 60455-760, Brazil
´
Correspondence should be addressed to J. C. Moreno-Pirajan, jumoreno@.co
Received 15 May 2008; Accepted 23 June 2008
Recommended by Anatoly Rusanov
An adsorption microcalorimeter for the simultaneous determination of the differential heat of adsorption and the adsorption
isotherm for gas-solid systems are designed, built, and tested. For this purpose, a Cal
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