development of a novel solid-state sensor electrode based on titanium thin film as an indicator electrode in potentiometric and conductometric acid-base titration in aqueous solution开发的一种新型固态传感器电极基于钛薄膜作为指示电极电位和电导酸碱滴定溶液.pdfVIP

Hindawi Publishing Corporation Journal of Sensors Volume 2012, Article ID 681826, 8 pages doi:10.1155/2012/681826 Research Article Development of a Novel Solid-State Sensor Electrode Based on Titanium Thin Film as an Indicator Electrode in Potentiometric and Conductometric Acid-Base Titration in Aqueous Solution Nasser Abu Ghalwa Chemistry Department, Al Azhar University, Gaza, Palestine Correspondence should be addressed to Nasser Abu Ghalwa, dr.nasser.galwa@ Received 28 May 2012; Revised 2 October 2012; Accepted 7 October 2012 Academic Editor: Jiri Homola Copyright © 2012 Nasser Abu Ghalwa. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. A modified Ti/(SnO + Sb O ) electrode was prepared by thermal deposition on titanium substrate and its use as indicator 2 2 3 electrode to potentiometric and conductometric acid-base titration in aqueous solution at 298 K was developed. The E-pH curve is linear with slope of 0.0512 V/dec at 298 K. The standard potential of this electrode, E0 , was determined with respect to the SCE as reference electrode. The recovery percentages for potentiometric and conductometric acid-base titration for acetic acid against NaOH were calculated. The cell constant, specific conductance, and the molar conductance with dilution for some common electrolytes were measured. 1. Introduction in planar structures. The drawbacks of glass electrodes have led to intensive research for alternative pH electrodes. As a Proton sensitive met