抚顺煤热解过程中N2生成的实验研究(PDF).PDFVIP

41 11 西 安 交 通 大 学 学 报 Vol.41 11 2007 11 JOURNAL OF XIAN JIAOTONG UNIVERSITY N ov. 2007 N2 , , , ( , 710049, ) : 利用固定床反应器在600 1 300 ! 范围内进行抚顺煤的热解实验, 研究 热解过程中燃料 N 向N2 的转化, 以及脱除矿物质元素和添加催化剂对N2 生成的影响. 升温速率是20 ! / min, 热 解载气为高纯He, 热解产生的N2 用气相色谱方法定量分析. 实验结果表明, 抚顺原煤在600 ! 热 解时N2 生成量很少, 不足 10%. 随着热解温度的进 一步升高, 煤中N 向N2 的转化率几乎呈线性 2 增长. N 的来源 一是直接从煤的大分子结构中释放, 二是由矿物质元素与燃料氮之间的固相反应 产生. 抚顺煤脱除矿物质后热解时, N2 的生成量明显减少. TiNaKFeCa 类矿物质元素的加入 不同程度地促进 N2 生成, 而且其作用温度区间各不相同. : N2 生成; 气相色谱方法; 热解; 脱除矿物质; 催化剂 : TK16 : A : 0253987X( 2007) Experimental Investigation on N Formation During 2 Pyrolysis of Fushun Coal Yao Mingyu, Yan Xiao, Liu Yanhua, Che Defu ( School of Energy and Pow er Engineering, Xian Jiaotong U niversity, Xian 710049, China) Abstract: T he formation of N2 during pyrolysis of Fushun coal with and without catalyst was in vestigated in a fixedbed reactor with a heating rate of 20 ! / min up to 1 300 ! . N2 emission was measured by a gas chromatograph. pyrolysis experiment show s that a little N2 releases below 600 2 ! ,while N emission increases linearly with the temperature over 600 ! . T he demineralization dramatically changes N2 formation profiles and reduces nitrogen conversion to N2 . Addition of 3% (mass fraction) catalyst promotes N2 formation of the demineralized coal, but the catalytic effect depends on temperature and the species of mineral matter . Ti, Fe, K and Ca enhance N2 2 emission significantly, but the effects of N a and Mg on N formation