几种酰胺类除草剂的光降解及其致突变性-环境科学.PDF

1999 7 ENVIRONM ENTA L SCIENCE July , 1999 * 王琪全　　彭展雄 ( , 310027) 3 , Ame . , , 3 , : . ; , , . , , , , , , Ame . The Photodegradation of Three Kinds of Amid Herbicides and Their Mutagenicity* Wang QiquanPeng Zhanx iong (In titu te of Environment and Re our ce Chemi try ,Zhejiang U nivercity, Hangzhou310027, China) Abstract T he photodegradatio n of aceto chlor , metolachlor and but achlor w a t udied. T he mutag enicity of . the e thr ee herbicide and their photo degradation pro duct w er e det ermined by A me te t T he r e ult how ed . that the photodegradatio n dynamic of the e tr ee her bicide obey ed fir t or der T he or der of degradation rat e con tant wa : metolachlor acetochlor buta chlor . A ceto chlor and it photodegradatio n pr oduct exi t ed no mutag enicity , while metolachlor and butachlor how ed mutag enicity . It eemed t hat there w a no other muta- genic ub t ance gener ated during t he photo degr adation of metolachlor . In the end of the phot odegr adatio n period of butachlor , ome other mutag enic ub tance gener ated. , , , , , . Keywords amid her bicide acetochlor met olachlor butachlo phot odegr adat ion Am e t e t 98% . , , [ 13] 98% . , , HPLC . [ 1, 4] . , [ 1, 47] ( 2) Spectr a-Phy ic , 100 - , , Spectra UV V IS 3 . YWG C18 1020cm , 1. 0cm / min. . , 220nm,