O2CO2煤粉燃烧时含铁矿物质转化行为的实验研究.pdfVIP

第36 卷第4 期 燃料化学学报 Vo1. 36 NO.4 2ω8 年8 )4 Journal of Fuel Chemistry and Technology Aug. 2佣8 文章编号:ω53-2斜)9(2仰的04415，(记 C0 0 / 2 煤粉燃烧时含铁矿物质转化行为的实验研究 2 李意，盛昂栋 (东南大学，能源与环境学院，江苏南京 21 ∞96) 摘 要要:通过乌兰木伦煤和哈拉沟煤在沉降炉中的燃烧实验，采用57 Fe Mösshauer 谱仪，对煤中含铁矿物质及其在 0/风和 C0 02/ 2 燃烧条件下生成的』延中含铁成分进行分析和比较，研究了 02/C02 煤粉燃烧时含铁矿物质的转化行沟。结果表明，与 N 02/ 2 燃烧相比，0/C0 燃烧对灰中生成的主要含铁矿物相种类没有影响，{ê.显著地改变了灰巾含铁矿物相的相对含最; 2 C0 02/ 2 燃烧更有利于内在黄棋矿和菇铁矿生成硅酸盐璇璃体阳不是氧化成铁氧化物。 1庭中含铁矿物相的相对含量变化表 C0 C0 明 02/ 2 燃烧影响煤的结淹跑势，对于含内在含铁矿物较多的煤，02/ 2 燃烧会增加其结渣的趋势。 关键词:煤粉; 02/C02 燃烧;含铁矿物质;转化行为; 57 Fe Mössbauer 谱 中回分提号: TQ534 :st献标识码 :A Experimental study on transfonnation behaviors of iron.bearing minerals during Oz/COz combustion of pulverized coal LI Yi , SHENG Chang-dong (Sc加01 01 Energy Environment , Southeast Universi纱， ， Nanjing 21ω俑， China) Abstract: The transformation behavíors of iron-bearing mínerals during O/C02 combustion of pulverized coat usere studíed through combustíon experiments of by burning wulanmulun coal and halagou coal in a drop tube fumace. 57Pe Mössbauer spec1roscopy was employed 10 characterize and compare in detail the íron附bearing components present ín the ashes formed ín 02/N2 and 02/C02 combustion as weJl as those occurring in the parent coals. It was found that , in comparison with 02/N2 combustion , O/C02 combustion does not lffect the iron-bearing phases formed , however , it does affect their relative amounts in the ashes. 02!C02 combustion favors the inc1 uded