TeO2-B2O3-BaO系统玻璃的形成区及其析晶行为.pdfVIP

Vo l. 41 No.4 华东理工大学学报(自然科学版) 471 2015户08 lournal of East China University of Science and Technology (Natural Science Edition) 文章编号:1006-3080(2015)04-0471-06 B Ba Te02- 203- O 系统玻璃的形成区及其析晶行为 张明， 张培忠， 胡一晨， 王 淳， 潘晓丹， 张秋月 (华东理工大学材料科学与工程学院，上海 200237) 摘要:利用浮冷法、差热分析(DTA) 、 X 射线衍射(XRD) 和拉曼光谱研究了 Te02-B203-BaO 玻璃的形成区和析晶行为。结果显示二元系统容易析出晶体，如 y-Te02 、 α-Te02 、 BaTe409 和 BaTe 05 等，而三元系统玻璃有较宽广的玻璃形成范围和较强的抗析晶能力，适用于崎酸盐玻璃光 2 纤的皮料。 关键词:Te02-B2 03-BaO 玻璃;玻璃形成区;析晶行为 中图分类号:TQ171 文献标志码:A Glass Forming Region and Crystallization Behavior of Te02-B203-BaO Glass ZHANG Ming , ZHANG Pei-zhong , HU Yi-chen , WANG Chun , PAN Xiao-dan , ZHANG Qiu-yue (School of Materials Science and Engineering , East China University of Science and Technology , Shanghai 200237 , China) Abstract: Glass forming region and crystallization behavior of Te02-B203-BaO glass were studied by quenching method , differential thermal analysis (DTA) ,X-ray diffraction (XRD) and Raman spectrum. The results showed that crystals like y- Te02 ， αTe02 BaTe409 and BaTe2 0 5were precipitated in binary system. However , glass forming region for the ternary system is satisfactorily large and devitrification tendency of the glasses in the region has been improved , indicating that the glass might be potential cladding glass of tellurite optical fiber. Key words: Te02-B203-BaO glass; glass forming region; crystallizati