高钠煤水热脱钠处理及其对燃烧特性的影响-燃料化学学报.PDF

第42卷 第12期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No.12 2014年12月 Journal of Fuel Chemistry and Technology Dec. 2014 文章编号:0253鄄2409(2014)12鄄1416鄄07 高钠煤水热脱钠处理及其对燃烧特性的影响 赵摇 冰,王嘉瑞,陈凡敏,王小悦,李小江 (华电电力科学研究院,浙江 杭州摇 310030) 摘摇 要:以五彩湾高钠煤为研究对象,根据煤中钠的赋存形态,分别研究了不同条件下水洗和水热处理两种方式对碱金属的 脱除效果,同时考察了水热处理对煤燃烧特性的影响。 结果表明,五彩湾煤中钠主要以水溶性钠盐存在;单纯水洗对Na 的脱 除效果不理想,并且工艺耗时长、耗水量大;水热处理脱钠效率高,钠脱除率高达90.5%,处理后的煤灰中Na O含量降至 2 0.7%,属于低钠煤范围;水热处理后煤样的燃烧速率曲线移向低温区,燃烧特性优于原煤。 关键词:高钠煤;赋存形态;脱钠;燃烧特性 中图分类号:TQ536.1摇 摇 文献标识码:A Hydrothermal treatment to remove sodium from high sodium coal and its influence on combustion characteristics ZHAO Bing,WANG Jia鄄rui,CHEN Fan鄄min,WANG Xiao鄄yue,LI Xiao鄄jiang (Hua Dian ElectricPowerResearchInstitute,Hangzhou摇 310030,China) Abstract:Consideringtheformof sodiumexistingincoal,seriesofwater washingandhydrothermaltreatments were used to remove alkali metals from a high sodium coal from Wucaiwan. The variation of combustion characteristics of coal after pretreatment was investigated. The results show that the sodium in the coal mainly existsaswater鄄soluble form. The Na removal ratio by water washing treatment does not reach the expectation with the characteristics of time consuming and high water consumption. The hydrothermal treatment is effective in sodium removal as high as 90.5%,and Na O content in the ash decreases to 0.7% which belongs to the 2 scope of low sodium level in coalash. Theburning curvesof coal samplesafter hydrothermaltreatment moveto the low temperature zone,and the combustion characteristicsisimproved compared with raw coal. Key words:high sodium coal;existing form;sodium remove;combustion characteristics