低温浓缩-气质联用分析污染源废气中环氧氯丙烷.pdfVIP

第9 卷第2 期 环境监控与预警 Vo 1. 9 ,No.2 2017 年4 月 Environmental Monitoring and Forewarning April2017 DOI: 10. 3969/j. issn. 1674-6732.2017.02.006 低温浓缩-气质联用分析污染源废气中环氧氯丙院 宋晓娟，李海燕，尹明明，马玉琴 (连云港市环境监测中心站，江苏 连云港 222001) 摘 要:建立了气袋采样-液氮低温浓缩-气质联用分析污染源废气中环氧氯丙烧的方法，优化了相关监测参数。优化后 的方法在环氧氯丙烧质量浓度 10 -500μg/旷范围内线性良好，相关系数 0.999 ，加标回收率为 72.1% -85.7% ，相对标 3 准偏差 5 %，气体进祥量为 5.0mL 时，检出限为 4.37μg/m ，可以满足废气中环氧氯丙炕监测的要求。 关键词:低温浓缩;气质联用;环氧氯丙炕 1 中固分类号:X831;0657.7+ ;0657.63 文献标志码:B 文章编号:1674 -6732(2017)02 -0023 -04 Determination of Epichlorohydrin Emissions from Stationary Sources Using Cryogenic Pre- concentration Followed by GC/MS SONG Xiao-juan , LI Hai-yan , YIN Ming-ming , MA Yu-qin (Lianyungαng Environmentα1 Monitoring Center , Liαnyunga晤， Jiαngsu 222001 , Chinα) Abstract: A method based on c可ogenic pre-concentration followed by GC/MS was established for the determination of epichloro- hydrin emissions from slationary sources. A cryogenic pre-concentrator , which acts as aUlosampler , was used 10 concentrale epichlo- rohydrin collected in gas bags. Relevant parameters for cryogenic pre-concentration were optimized. After pre-concentrated , epichlo- rohydrin was introduced into GC/MS to undergo qualitative and quantitative analysis , and appraisal of Ihe whole method was then carried out from different respects. Good linearity was obtained within 10 - 500μgI旷， and the correlation coefficient was greater than O. 999. The average recoveries ranged from 72. 1 % - 85. 7 %. Meanwhile , the method was stable enough to realize extensive 3 use with RSD lower than 5%.