含芳香侧链梳形聚合物对沥青质聚集行为的影响盖德成厉涛邹润.DOC

含芳香侧链梳形聚合物对沥青质聚集行为的影响 盖德成，厉涛，邹润，许军*，李莉，郭旭虹 （华东理工大学 化学工程联合国家重点实验室，上海 200237） 摘要：-α-烯烃）侧链接枝芳香基团（苯胺、萘胺及2-氨基苯并咪唑）的梳形聚合物（AMAC、NMAC和MACB）。利用UV-vis、浊度仪、DLS、偏光显微镜分别表征三种梳形聚合物对沥青质的初始沉淀点、粒径分布和聚集行为的影响。结果表明，添加50 ppm同等接枝率的聚合物对沥青质的分散效果为：NMAC＞AMAC＞MACB。沥青质在模型油中的“初始沉淀点”最大增幅约为20%。平均粒径减小一半，且分布变窄。其微观聚集状态也由高聚集尺寸的絮凝态向低聚集尺寸的分散态转变。梳形聚合物能使沥青质更稳定地分散悬浮，对稠油的采输有现实的应用意义。 关键词：稠油沥青质；聚集行为；梳形聚合物；初始沉淀点 TQ 316.343 Effect of comb-type copolymer with aromatic side chains on asphaltene aggregation behavior Gai De-cheng, Li Tao, Zou Run, Xu Jun*, Li Li, Guo Xu-hong (State-Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237) Abstract： Comb poly(maleic anhydride-co-α-olefin)s derivatives with phenyl, naphthyl and benzimidazole pendants (AMAC, NMAC and BMAC) were synthesized. The effect of comb-polymers on the onset of deposition, aggregation behavior and size distribution of asphaltenes in model oil were studied by means of UV-vis, turbidity meter, DLS and polarizing microscopy. The results show that the polymer additives have different effects on the asphaltene aggregation behaviors. When the grafting density of copolymers is similar and the asphaltene concentration is 50 ppm, asphaltenes were dispersed most by NMAC, the next is AMAC, and the least is MACB. By NMAC, the “onset of asphaltene deposition” is postponed by about 20%. The average size of aggregates was reduced half and the distribution was narrowed. The microscopic aggregation morphology of asphaltenes also was changed from the large-sized flocculated aggregates to the small-sized dispersed aggregates. By these copolymers, asphaltenes can be well dispersed in the oil, indicating that they are good candidate for the additives for the recovery and transportation of heavy oil. Keywords: asphaltenes in heavy oil; aggregation behavior; comb-type copolymer; onset of asphaltene deposition 近年来，非常规油气资源的开发成功，给全球原油价格带来巨大冲击。同样，以稠油为代表的非常规原油以其储量丰富，分布集中而同样具有巨大的发掘潜力。然而，由于较高的沥青质和硫含量使得稠油在开采、运输和炼化过程中普遍存在粘