acylated 2-(n-arylaminomethylene)benzo[b]thiophene-3(2h)-ones molecular switches with varying migrants and substituentsacylated 2 -(n-arylaminomethylene)苯并[b]thiophene-3(2 h)的分子开关取代基不同移民和.pdfVIP

Hindawi Publishing Corporation International Journal of Photoenergy Volume 2009, Article ID 694196, 6 pages doi:10.1155/2009/694196 Research Article Acylated 2-(N-arylaminomethylene)benzo[b]thiophene- 3(2H)-Ones: Molecular Switches with Varying Migrants and Substituents Alexander D. Dubonosov,1 Vladimir P. Rybalkin,1 Lydia L. Popova,2 Alexey V. Tsukanov,1 Yurii V. Revinsky,2 Vladimir A. Bren,2 and Vladimir I. Minkin1, 2 1 Southern Scientific Center of Russian Academy of Sciences, 344006 Rostov on Don, Russia 2 Institute of Physical and Organic Chemistry, Southern Federal University, 344090 Rostov on Don, Russia Correspondence should be addressed to Alexander D. Dubonosov, aled@ipoc.rsu.ru Received 9 February 2009; Revised 7 May 2009; Accepted 22 May 2009 Recommended by Mohamed Sabry Abdel-Mottaleb Synthesis and properties of photochromic acylated 2-(N -arylaminomethylene)benzo[b]thiophene-3(2H )-ones are described. Their structure largely depends on the nature of acyl migrant and in a less degree on N-aryl substituent. Copyright © 2009 Alexander D. Dubonosov et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 1. Introduction (V = 2 · 10−3 L) was carried out by filtered light of a high- pressure mercury lamp DRSh (250 W) supplied with a set of 2-(N -Acyl-N -arylaminomethylene)benzo[b]thiophene- glass filters (λirr = 436 nm). The intensity of light used for 3(2H )-ones represent a new family of photochromic