square wave voltammetry for analytical determination of cadmium in natural water using ca10(po4)6(oh)2-modified platinum electrode方波伏安法分析测定镉的自然水使用ca10(po4)6(oh)2-modified铂电极.pdf

American Journal of Analytical Chemistry , 2010, 1, 150-158 doi:10.4236/ajac.2010.13019 Published Online November 2010 (http://www.SciRP.org/journal/ajac) Square Wave Voltammetry for Analytical Determination of Cadmium in Natural Water Using Ca (PO ) (OH) -Modified Platinum Electrode 10 4 6 2 1* 2 3 Moulay Abderrahim El Mhammedi , Mounia Achak , Mina Bakasse 1 Equipe de Chimie Anlaytique et Modélisation Statistique, Faculté Polydisciplinaire, Université Hassan 1er, Khouribga, Morocco 2Laboratoire d ’Hydrobiologie et d ’ Algologie, Faculté des Sciences Semlalia, Université Cadi Ayyad, Marrakech, Morocco 3Equipe d ’Analyse des Micro-Polluants Organiques, Faculté des Sciences , Université Chouaib Doukkali, El Jadida, Morocco E-mail : elmhammedi@yahoo.fr Received June 29, 2010; revised August 2, 2010; accepted October 26, 2010 Abstract This paper reports on the development of a novel electrochemical assay for cadmium (II) in natural water, which involves the use of disposable hydroxyapatite modified platinum electrode (HAP/Pt). Cadmium (II) was preconcentrated on the surface of the modified electrode and adsorbed onto HAP and oxidized at E = –680 mV. The HAP-modified platinum electrode exhibited superior performance in comparison to the plati- num electrode and surprisingly, yielded a higher electrochemical response. The best defined anodic peak was obtained with 0.2 mol L-1 KNO pH 5.0 after 25 min of accumulation time