structure and electrical properties of oxide doped rhombohedral pb(ni13nb23)o3-pbtio3 ferroelectric ceramics结构和电子性质的氧化物掺杂菱形的pb(ni13nb23)o3-pbtio3铁电陶瓷.pdf

Materials Sciences and Applications, 2010, 1, 66-71 doi:10.4236/msa.2010.12012 Published Online June 2010 (http://www.SciRP.org/journal/msa) Structure and Electrical Properties of Oxide Doped Rhombohedral Pb(Ni Nb )O -PbTiO 1/3 2/3 3 3 Ferroelectric Ceramics  Bijun Fang , Dun Wu, Qingbo Du, Limin Zhou, Yongyong Yan School of Materials Science and Engineering, Changzhou University, Changzhou, China. Email: fangbj@ Received February 28th, 2010; revised May 3rd, 2010; accepted May 5th, 2010. ABSTRACT 0.7Pb(Ni Nb )O -0.3PbTiO (0.7PNN-0.3PT) and 1 mol% La O -, Y O -, ZnO-, MnO - and Nb O -doped 0.7PNN- 1/3 2/3 3 3 2 3 2 3 2 2 5 0.3PT ferroelectric ceramics were prepared by the conventional solid-state reaction method via the columbite precursor route. The ceramics sintered at 1180℃ exhibit pure rhombohedral perovskite structure except the Y O -doped 2 3 0.7PNN-0.3PT ceramics. The oxide-doped 0.7PNN-0.3PT ceramics exhibit rather homogeneous microstructure and improved densification, especially for the MnO -and La O -doped 0.7PNN-0.3PT (defect) ceramics whose relative 2 2 3 density is larger than 96%. All the above dopants decrease the dielectric loss of the 0.7PNN-0.3PT ceramics, whereas the values of the dielectric maximum ( ) and the temperature of  (T ), and the character of dielectric response vary m