steady-state and time-resolved fluorescence studies of anthrylacrylic ester稳态和时间分辨荧光anthrylacrylic酯的研究.pdf

Open Journal of Physical Chemistry , 2012, 2, 212-220 /10.4236/ojpc.2012.24029 Published Online November 2012 (http://www.SciRP.org/journal/ojpc) Steady-State and Time-Resolved Fluorescence Studies of Anthrylacrylic Ester 1 1* 2 3 Anil B. Naik , L. R. Naik , V. Jayathirtha Rao , Haridas Pal 1Department of Studies in Physics, Karnatak University, Dharwad, India 2Organic Division II, Indian Institute of Chemical Technology, Hyderabad, India 3Radiation and Photochemistry Division, Bhabha Atomic Research Centre (BARC), Mumbai, India * Email: naik_36@ Received July 26, 2012; revised August 25, 2012; accepted September 27, 2012 ABSTRACT The photophysical properties of Anthrylacrylic ester were investigated in various solvents using steady-state and time- resolved fluorescence techniques. The dual fluorescence was observed in various solvents of different polarity functions. The emission bands observed are around 400 nm (band I) and 480 nm (band II) for 350 nm and 390 nm excitation at low concentrations (10–5 mol·dm–3) but at higher concentrations (10–3 mol·dm–3) only the emission (band II) at 480 nm alone was observed. The emission band observed around 400 nm shifts from 390 nm to 420 nm (shift 30 nm) when the excitation wavelength was varied from 300 nm to 380 nm and the emission band at 480 nm shifts from 430 nm to 510 nm (shift 80 nm) for the change of excitation wavelength from 380 nm to 400 nm. However, both emissions were observed for 380 nm excitation at lower concentrations. Solvatochromic shifts of electronic absorption and