燃煤电厂超低排放改造前后汞污染排放特征研究-环境科学研究.docVIP

【二审修改稿】 燃煤电厂超低排放改造前后汞污染排放特征研究 摘要:针对300MW燃煤机组，30B汞监测方法通过多点监测对比了实施低氮燃烧器改造、SCR脱硝改造、新增低温省煤器、静电除尘器高频电源改造、湿法脱硫塔脱硫提效并增加管式除雾、新增湿式静电除尘器技术路线开展的超低排放改造前后汞排放及分布特征。研究表明：49μg/kg，ρ(Hg)测量值为1.87μg/m3；煤燃烧及经过污染物控制单元后，35.0%，29.5%，35.4%，30μg/kg，ρ(Hg)测量值为0.46μg/m3；脱硫进水及湿式除尘器进水对汞平衡几乎没有影响，，36.1%，55.2%，8.7%，， 关键词：燃煤电厂；超低排放；汞排放 中图分类号：X705 文献标志码：A Mercury emission characteristics from the coal-fired power plant before and after ultra-low emission retrofitting Abstract: Based on the US EPA method 30B mercury monitoring methods, mercury emission and distribution of a 300MW coal-fired power plant were compared before and after ultra-low emission techniques, which include retrofitted low NOx burner, SCR, ESP with high frequency power source, FGD with tubular mist eliminator and added low temperature economizer and WESP. Mercury content of the coal is 49μg/kg, and the mercury concentration at the stack entrance is 1.87μg/m3, before the retrofitting. After the air pollutant control devices，35% of the mercury from coal combustion exists in ashes, 29.5% of the mercury in gypsum, and 35.4% of the mercury discharge from the stack. After ultra-low emissions retrofitting, mercury content of the coal is 30μg/kg, and the mercury concentration at the stack entrance is 0.46μg/m3. After coal combustion and pollutant control devices, 36.1% of the mercury exists in ashes, 55.2% of the mercury in gypsum, and 8.7% of the mercury discharge from the stack. After retrofitting, more mercury has been captured by APCD system compared that before retrofitting. The capture efficiency was increased to 1.5 times. This may be due to the higher oxidation rate from elemental mercury to oxidized mercury in the SCR system and better capture oxidized mercury in the WFGD system. WESP did not show any significant effect on the Mercury capture efficiency. Key words:coal-fired power plant; ultra-low emission; mercury emission　  燃煤发电是我国电力供应的主要来源，但发电过程的煤炭燃烧也是大气环境污染严重的重要原因。2013年以来，中国发电企业主动倡导、推动了燃煤电站“近零排放”?“超低排放”[1]，通过对烟尘、二氧化硫、氮氧化物等常