稻壳灰制备介孔分子筛的改性及其吸附性能研究.docVIP

稻壳灰制备介孔分子筛的改性及其吸附性能研究 摘要以稻壳灰为硅源提取二氧化硅合成介孔材料MCM-41，并用三甲基氯硅烷对其进行改性。将改性前后的材料通过X-射线粉末衍射分析（XRD）、N2吸附-脱附、扫描电镜（SEM）和傅里叶变换红外光谱（FTIR）进行表征，并用于吸附模拟废水中的2,4-DNT。结果显示，改性前后的材料均具有长程有序的六方介孔结构和较高的有序度。Freundlich和Langmuir等温吸附模型均能较好地拟合两种材料的吸附等温线。二者的吸附动力学均可以用伪二级动力学方程拟合。溶液中2,4-DNT的去除率与两种材料的投加量均呈正相关关系。改性前材料的吸附效果随pH的升高而降低，而改性后材料的吸附效果在pH=7时最佳。经热力学和动力学分析认为改性后材料的吸附过程既存在物理吸附又存在化学吸附。6019 关键词稻壳灰MCM-41改性吸附 毕业设计说明书（论文）外文摘要 TitleThe modification of mesoporous molecular MCM-41 synthetized from rice husk ash as itrsquo;s silica source and their application to adsorption of 2,4-Dinitrotoluene Abstract Mesoporous MCM-41 was synthesized using rice husk ash (RHA) as the silica source and then it was modified by reacting with trimethylchlorosilane. These two kinds of material were characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM), N2 adsorption-desorption and Fourier transform infrared spectroscopy (FTIR). Then they were used to adsorb 2,4-Dinitrotoluene from aqueous solution. Both Freundlich isotherm and Langmuir isotherm could be fitted well with the two kinds of materialrsquo;s adsorption isotherms. Both the adsorption kinetics could be fitted with pseudo-second kinetic equation well. There was a positive correlation between the removal efficiency and the dosage of both kind of material.For MCM-41, the adsorption capacity was reduced with the increase of pH. But for modified MCM-41, the adsorption capacity was best at pH=7. Analysts believed that both physical adsorption and chemical adsorption exist in the adsorption process of the modified materials. 3结果与讨论10 3.1材料的表征10 3.1.1RHMCM-41的表征10 3.1.2CH3-MCM-41的表征12 3.2RHMCM-41的吸附性能15 3.2.1吸附动力学15 3.2.2吸附等温线16 3.2.3吸附热力学18 3.2.4pH的影响19 3.2.5投加量的影响20 3.3CH3-MCM-41的吸附性能21 3.3.1不同条件下的材料性能比较21 3.3.2吸附动力学22 3.3.3吸附等温线24 3.3.4吸附热力学25 3.3.5pH的影响26 3.3.6投加量的影响27 3.3.7吸附机理28 结论29 致谢30 参 考 文 献31 1引言 1.12,4-DNT概述 2,4-二硝基甲苯（2,4-DNT）是一种重要的有机化工中间体，广泛应用于染料、油漆、涂料的制备，也是生产炸药的主要原料。2,4-二硝基甲苯对水生生物有毒害作用，被其污染的水体略带苦的金属味，呈淡黄色。当浓度达10mg/L时，可造成鱼类及水生物