异硫氰酸酯的制备和应用_谢兵.pdfVIP

20 3 Vol.20, No .3 2006 3 　　　　　　　　　　　　Chemical Industry Times 　　　　　　　　　　　　Ma r.3.2006 1, 2 3 谢　兵 , 周光明 (1., 550025; 2.,,550025,3., 400715) 　, 。 　　　　 　 Preparation and Applications of Isothiocyanates Xie Bing1, 2 　Zhou Guangming3 (1.Key Laboratory of Green Pesti ide and Agri ultural Bio1ongi al Engineering Ministry of Edu ation,Resear h and Development Centre of Fine Chemi als,Guizhou University,Guizhou Guiyang 550025;2.College of Chemistry and Environmental Seien e,Guizhou University for Nationalites,Guizhou Guiyang 550025,China S hoo1 of Chemistry and Chemi al Engineering,Southwest University,Chongqing 407715) Abstract 　Pro edures for the preparation of isothio yanates were synthesized in this paper.The appli ations of isothio- yanates in the hetero y li synthesis and biote hnology were introdu ed . Keywords 　isothio yanate　hetero y li ompound　preparation　appli atin NaSCN,CH Cl 　　, 2 2 RBr RNCS , PEG—200, 1h , , [2] 。 ,、,; CS 1 1 2 1 R P +R N R P=NR R NCS 。 3 3 3 1.2 　 。、 , 、、 。 [3、4]