solid state 13c and 1h mas nmr investigations of c60(ferrocene？d10)2 complex固体13 c和1 h mas nmr调查c60(二茂铁 d10)2复杂.pdfVIP

Spectroscopy 17 (2003) 39–44 39 IOS Press Solid state 13C and 1H MAS NMR investigations of C (ferrocene-d ) complex 60 10 2 E. Shabanova, K. Schaumburg and F.S. Kamounah ∗ CISMI, Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark Abstract. The article presents NMR investigations of a molecular crystalline material C (ferrocene-d ) , which consists of 60 10 2 two highly mobile molecules. 13C and 1H NMR line shapes and T1 relaxation times are discussed and compared with results obtained for the undeuteriated compound. The mobilities of C60 and ferrocene molecules were found to increase in the complex in comparison with the two components as crystalline materials. Keywords: Molecular crystal, plastic crystal, C60 , ferrocene, 13C and 1H NMR 1. Introduction Molecules in crystalline C60 [1,2] and ferrocene [2–5] have been shown to carry out a rapid rotations at room temperature. The mobilities of the molecules have been found to be changed when they are combined in the crystalline complex C60(ferrocene)2 [2] (Fig. 1). A more complete description of the molecular mobility can be obtained by extension of the NMR investigations to include the deuteriated material C (ferrocene-d ) . Here it is possible to neglect nuclear dipolar interactions. Therefore, com- 60 10 2 paring the results for deuteriated and undeuteriated complexes it should be possible to separate dipolar 1H contributions from other interactions. To explore the dynamical properties of the ferrocene molecules