synthesis and characterization of new photoluminescent oxadiazolecarbazole-containing polymers新发光oxadiazolecarbazole-containing聚合物的合成和表征.pdfVIP

Hindawi Publishing Corporation International Journal of Polymer Science Volume 2010, Article ID 581056, 6 pages doi:10.1155/2010/581056 Research Article Synthesis and Characterization of New Photoluminescent Oxadiazole/Carbazole-Containing Polymers Simona Concilio,1 Valeria Bugatti,1 Pio Iannelli,2 and Stefano Piotto Piotto2 1 Department of Chemical and Food Engineering, University of Salerno, Via Ponte Don Melillo, 84084 Fisciano, Italy 2 Department of Pharmaceutical Science, University of Salerno, Via Ponte Don Melillo, 84084 Fisciano, Italy Correspondence should be addressed to Simona Concilio, sconcilio@unisa.it Received 5 November 2009; Accepted 14 March 2010 Academic Editor: Jinying Yuan Copyright © 2010 Simona Concilio et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. We report on the synthesis and the characterization of a new class of segmented polyethers POC containing the oxadiazole and carbazole units. The polymers exhibit a high thermal stability, high glass transition temperatures, and good solubility in common organic solvents, despite the extended aromatic portion in the main polymer chain. The synthetic procedures are simple, and no acid side-products are obtained. According to previous reports on oxadiazole/carbazole-containing materials, POCs show high photoluminescence activity in the blue region of the visible spectra. The good solubility in chlorinate solvents allows the preparation of films with homogeneous thickness by spin coating. Glass transition temperature in the range 115–125◦C ensures good stability of film morphology at room temperature. The only