synthesis and photochromism of quinolines and benzo[h]quinolines of 1,3-diazabicyclo[3.1.0]hex-3-ene喹啉类药物合成和对光反应变色和苯并[h]喹啉类药物,3-diazabicyclo[3.1.0]hex-3-ene.pdfVIP

Hindawi Publishing Corporation International Journal of Photoenergy Volume 2011, Article ID 218427, 6 pages doi:10.1155/2011/218427 Research Article Synthesis and Photochromism of Quinolines and Benzo[h]quinolines of 1,3-Diazabicyclo[3.1.0]hex-3-ene Nosrat O. Mahmoodi,1 Elham Asadollahi,1 Hamzeh Kiyani,2 and Nahid Naseri1 1 Department of Chemistry, University of Guilan, Namjoo street, P.O. Box 41335-1914, Rasht, Iran 2 School of Chemistry, Damghan University, P.O. Box Damghan, Iran Correspondence should be addressed to Nosrat O. Mahmoodi, nosmahmoodi@ Received 11 May 2011; Revised 28 June 2011; Accepted 6 July 2011 Academic Editor: Ignazio Bellobono Copyright © 2011 Nosrat O. Mahmoodi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 1,3-Diazabicyclo[3.1.0]hex-3-ene systems represent a very interesting class of organic materials, possessing unique photochromic properties in the solid state. It has been demonstrated that these compounds form deeply colored, fairly stable materials under UV radiation. Here, for the first time we report synthesis of several 1,3-diazabicyclo[3.1.0]hex-3-enes with premade substituted quinoline and benzo[h]quinoline rings. 1. Introduction dinitrobenzylpyridines, diphenylmaleonitriles, triarylimida- zole dimers, aziridines, diarylethenes, diarylperfluorocy- Photochromism is defined as light-induced reversible trans- clopentenes, and biindenylidenedione derivatives. Among formation of a chemical species between two isom