SYLLABUS Jodhpur National University（教学大纲焦特布尔国立大学）.pdfVIP

SYLLABUS MASTER OF SCIENCE CHEMISTRY JODHPUR NATIONAL UNIVERSITY JODHPUR MASTER OF SCIENCE CHEMISTRY YEAR I Paper I INORGANIC CHEMISTRY Paper II ORGANIC CHEMISTRY Paper III PHYSICAL CHEMISTRY Paper IV GROUPTHEORY, SPECTROSCOPY AND DIFFRACTION METHODS YEAR II Paper V SPECTROSCOPY PHOTOCHEMISTRY AND SOLID STATE CHEMISTRY Paper VI BIO- INORGANIC, BIO- ORGANIC BIO- PHYSICAL CHEMISTRY Paper VII ORAGANIC SYNTHESIS Paper VIII PHOTOINORGANIC CHEMISTRY Paper IX INDUSTRY BASED ENVIRONMENTAL STUDIES Paper I INORGANIC CHEMISTRY Unit I Stereochemistry and Bonding in Main Group Compounds: VSEPRT, Walsh diagram (tri- and penta- atomic molecules), dπ –p π bonds, Bent rule and energetics of hybridization, some simple reactions of covalently bonded molecules. B.Metal-Ligand Equilibria in Solution Stepwise and overall formation constants and their interaction, trends in stepwise constant, factors affecting the stability of metal complexes with reference to the nature of metal ion and ligand. Chelate effect and its thermodynamic origin, determination of binary formation constants by pH- metry and spectrophotometry Unit II Reaction Mechanism of Transition Metal Complexes: Energy profile of a reaction, reactivity of metal complex, inert and labile complexes, kinetic application of valence bond and crystal field theories, kinetics of octahedral substitution, acid hydrolysis, factors affecting acid hydrolysis, base hydrolysis, conjugate base mechanism, direct and indirect evidences in favour of conjugate mechanism, anation reactions, reactions without metal ligand bond cleavage. Substitution reactions in square planar complexes, the trans effect, mechanism of the substitution reaction. Redox reaction, electron tra