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Abstract
arethemost candidatesfor info肌ation
Diarylethenes promising high—density
and switchesbecauseoftheir
Storageoptical goodphotoch】广omic
thermal of excellent
isomerS,a11d
stability f.atigue
ofnovel oftheir areboth
synthesis diaD,lethenes嬲weU雒inVestigationsproperties
如ndamentalresearchaIld
hotspots.
In thisdissertation, new
thirty—fiVe unsymmetricalphotochromic
are are
cD,stals
pernuo卜diar),lethenecompoundssynthesized.TWen够-fiVediarylethene
theirStllJcturesof ofthemaredetemined
by
prepared,锄d twenty-two single—crystal
dimaction theefrectsofme
inVestigated heterocyclic
X-ray a11alysis.Wesystematically
the oftIle
aD,lringsspecies,tIleelectron-withdrawin∥donatingabili吼andposition
substituentsont11e oftllese
optoelectronicpmperties compouIlds.PreliminaD,
tests bom
holographicopticalStoragewe心pe而咖edusingdiarylethenesbearing
aIld media.TllemainiIuloVationachieVements
pyrrolethiophenerings舔recording
obtainedasfbllows:
1.Anewcl嬲sof b嬲edontlle
diarylethenes hybrid
unsymmetricalphotochr.omic
skeletonof moieties、Ⅳere meir
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