稻壳灰在丁苯聚合物水泥复合胶凝材料凝结硬化过程中的作用王茹.pdfVIP

第45 卷第2 期 硅 酸 盐 学 报 Vol. 45 ，No. 2 2 0 1 7 年 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY February ，2017 DOI ：10.14062/j.issn.0454-5648.2017.02.03 稻壳灰在丁苯聚合物/水泥复合胶凝材料凝结硬化过程中的作用 王 茹，王高勇，张 韬，李元哲 ( 同济大学材料科学与工程学院，先进土木工程材料教育部重点实验室，上海 201804) 摘 要：聚合物/水泥复合胶凝材料在解决普通水泥基材料脆性大、易开裂、抗拉抗折强度低等问题的同时还可使水泥基材料 具有了更好的防水性和耐久性，但聚合物/水泥复合胶凝材料凝结硬化较为缓慢。针对此，采用稻壳灰作为调凝组分，研究稻 壳灰对丁苯聚合物/水泥复合胶凝材料凝结硬化过程以及水化进程和水化产物的影响，探讨稻壳灰调节凝结硬化过程的机理。 结果表明：稻壳灰能加快丁苯聚合物/水泥复合胶凝材料的水化进程，缩短水化诱导期、加速期，并提高早期水化程度，从而 缩短凝结时间，提高早期强度。凝结硬化过程中，稻壳灰促进了C3S 的水化，并与部分水化产物Ca(OH)2 发生二次反应生成 C–S–H 凝胶。 关键词：聚合物；水泥；稻壳灰；丁苯乳液；凝结硬化；机理 中图分类号：TU528 文献标志码：A 文章编号：0454–5648(2017)02–0190–06 网络出版时间： 2017–01–18 21:53:04 网络出版地址：/kcms/detail/11.2310.TQ2153.016.html Function of Rice Husk Ash in Setting and Hardening Process of Styrene-Butadiene Rubber Latex/Cement Composite Cementitious Material WANG Ru, WANG Gaoyong, ZHANG Tao, RI Won Chol (Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Shool of Materials Science and Engineering, Tongji University, Shanghai 201804, China) Abstract: Rice husk ash was chosen to modify the composite cementitious materials. The effects of rice husk ash on the setting and hardening process, hydration process and hydration products of polymer/cement composite cementitious material was investigated, and the mechanism of controlling the setting and harden process by rice husk ash was also discussed. The results show that the rice husk ash can accelerate the setting and hardening process of styrene-butadiene rubber/cement composite cementitious material, shorten the induction period and acceleration period of hydratio