饱和Ca_OH_2溶液pH值对热镀锌钢表面锌酸钙覆盖层影响.pdfVIP

7 　　 /2010 9 　 Ca (OH )2 pH Effects of pH Value of Saturated Ca (OH )2 Solution on CaHZn Coating of Hot Dip Galvanized Steel 　, , ( , 5106 0) KONG Gang, CHEN Jiu-long, LU Jin-tang (School of M aterials Science and Engineering, South China University of Technology, Guangzhou 5106 0, China) :pH (9.0 ～ 12.0)Ca(OH)pH , 2 , 。 30 、、X 、:pH , ZnO , pH 9 , ZnO; ZnO , (R )、(R )、(R )(W ), i , p c ct s corr -1 2 icorr 10 μA/cm 。 :;;;; :TG 17 . 　　:A 　　:1001-381(2010)09-007 -06 Abstract:The change of the CaHZn layer and the corrosion behavior of the zinc coating in saturated Ca(OH )2 solution w ith decreased pH value from 9.0 to 12.0, w hich w as as simulations of the pore solution w ith reduced pH value by carbon dioxide, w ere investigated.And the dissolving mechanism of CaHZn under the experimental condition was also discussed.The prepared galvanized samples w ith CaHZn coating w ere immersed in saturated Ca (OH )2 solution w ith pH value 9.0-12.0 for 30 days, then studied with scanning electron microscope (SEM ), energy spectrum analysis (EDS ), X-ray dif- fraction (XRD), Tafel polarization and electrochemical impedance spectroscopy (EIS ).The results show that, w ith decreasing of pH value and increasing of the immersion time, the CaHZn decreases and the ZnO increases simultaneously .The entire surface of t