原创力文档conformational mobility of gox coenzyme complex on single-wall carbon nanotubes构象流动. gox辅酶复杂的碳纳米管对着单壁球长大.pdfVIP
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conformational mobility of gox coenzyme complex on single-wall carbon nanotubes构象流动. gox辅酶复杂的碳纳米管对着单壁球长大
Sensors 2008, 8, 8453-8462; DOI: 10.3390/s8128453
OPEN ACCESS
sensors
ISSN 1424-8220
/journal/sensors
Communication
Conformational Mobility of GOx Coenzyme Complex on Single-
Wall Carbon Nanotubes
Feng Liu 1,2, Xue-song Ye 1,2,*, Tao Wu 3,*, Chang-Tao Wang 1,2, Jia-wei Shen 3 and Yu Kang 3
1 Collage of Biomedical Engineering Instrument Science, University of Zhejiang, P.R. China. E-
Mail: fengliu@
2 Key lab of Biomedical Engineering of Ministry of Education, University of Zhejiang, P.R. China.
3 Department of Chemistry, University of Zhejiang, P.R. China. E-Mails: poopwill@;
kiddsuper@
* Author to whom correspondence should be addressed; E-Mails: yexs@;
tao_wu@; Tel: +86-571-879-510-90; Fax: +86-571-879-516-76
Received: 3 September 2008; in revised form: 30 November 2008 / Accepted: 4 December 2008 /
Published: 18 December 2008
Abstract: A critical issue in bioelectrochemical applications that use electrodes modified
by Single Wall Carbon Nanotubes (SWCNTs) is to ensure high activity of the catalytic site
of an immobilized enzyme protein interacting with nanomaterials. Since Flavin Adenine
Dinucleotide (FAD), a coenzyme of glucose oxidase (GOx), is the active center of the
catalytic site, conformation of which could determine the activity of enzyme, it is
important to understand the dynamic mechanism of its conformational mobility while GOx
is adsorbed on SWCNTs with multiple orientations. However, this dynamic mechanism
still remains uncle
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