ca含量的测定（Determination of Ca content）.docVIP

ca含量的测定（Determination of Ca content） Peoples Republic of China national standard Meat and meat products -- Determination of calcium content -- GB/T, 9695.13-88 Meat, and, meat, products-Method, for, determination, of, calcium Thought of thought, thought of thought - thought of thought 1, the subject content and scope of application This standard specifies the method for the determination of calcium in meat and meat products. This standard applies to the determination of calcium content in meat and meat products. 2 citation criteria GB 9695.19 sampling methods for meat and meat products 3 principle The sample is made into dilute hydrochloric acid solution after ashing, and the calcium ion and calcium oxalate ion form calcium oxalate in the weak acid solution Lake. After filtration, the precipitate dissolved in sulfuric acid solution, and then use the Potassium Permanganate standard solution titration for calcium oxalate ions Content. The reaction formula is: CaCl2 (NH4) 2C2O4 = CaC2O4: 2NH4Cl CaC2O4H2SO4 = CaSO4H2C2O4 5H2C2O42KMnO43H2SO4 = 2MnSO4K2SO410CO28H2O 4 reagent The reagents used are pure analytical, distilled water or water of considerable purity. 4.1 hydrochloric acid (GB 622): 1:1 solution. 4.2 sulfuric acid (GB 625): 1:5 solution. 4.3 sulfuric acid (GB 625): 1:24 solution. 4.4 methyl red (HG 3-958): 0.1% ethanol solution. 4.5 urea (GB 696). 4.6 ammonium oxalate (HG 3-976): 3% solution. 4.7 ammonium hydroxide (GB 631): 1:49 solution. Potassium Permanganate 4.8 (GB 643): 0.02N standard solution. 4.8. Potassium Permanganate with 1 standard solution: weigh in capacity of Potassium Permanganate 0.63g 2L Erlenmeyer flask, add water 1L dissolve, slow and warm, boil 1 ~ 2H, place in the dark place for the night, and then filter with G4 glass filter, the filtrate is stored in the clean, Dry brown reagent bottle, mix well. Potassium Permanganate 4.8.2 calibration standard solution Preparation of 4.8.2.1 0.02000N standard sodium oxalate solution: weigh in advance 10