纳米结构聚苯胺的合成及性质-南京师范大学学报（工程技术版）.PDF

9 2 () Vo.l 9 No. 2 2009 6 JOURNAL OF NAN JING NORMAL UN IVERSITY ( ENG INEERING AND TECHNOLOGY EDIT ION ) Jun, 2009 纳米结构聚苯胺的合成及性质 张 艳, 孙培培, 蒋晓青 ( , 210097) [ ] , , . . . . [ ] , , , , [ ] O 621. 3 [ ] A [] 1672-1292( 2009) 02-0041-07 Synthesis and Properties of Polyan ilineW ith Nanostructure Z hang Y an, S un Pe pi e,i J iang X iaoq ing ( School of Ch em istry nd Environm ent l Science, N njing N orm lUn iversity, N njing 210097, Ch in ) A bstrac t: B sed on the newest rese rch of poly n iline, th is p per summ ries the structures, properties, dop ing proper- ties of n no-structured poly n iline, nd especi lly introduces the different synthesizing m ethods in det i.l Conducting poly niline w ith n nostructure c n be successfully synthes ized by both chem ic l nd electrochem ic l routes. Chem ic l route includes v rious h rd-or soft-tem pl te synthesizing ppro ches nd tem pl te-freemethods. It deserved to be pointed out the interf ci l polym eriz tion nd r pid-m ixed re ction re new nd f cile temp l te-free ppro ches to ob t in l rge sc le nd high-qu lity n no-structured poly n iline w ith controll b le morphologies nd sizes. K ey w ord s: conducting polym ers, n nostructure, poly niline, synthesis, properties [ 1] 20 70, , . , () , . , [ 2, 3] . , , [ 4] [ 5] [ 6 ] . , , . 1 聚苯胺的结构 [ 7] 1987, M cD i rm id , : , y . y , , : y = 1 ( Leucoem er ldine, LE), ; y = 0 ( Pernigr n iline, : 2008-10-10. : ( . : ,, : .