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internal dynamics of dendritic molecules probed by pyrene excimer formation树枝状分子的内部动态探测的芘准分子的形成.pdf

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internal dynamics of dendritic molecules probed by pyrene excimer formation树枝状分子的内部动态探测的芘准分子的形成

Polymers 2012, 4, 211-239; doi:10.3390/polym4010211 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Review Internal Dynamics of Dendritic Molecules Probed by Pyrene Excimer Formation Jean Duhamel Institute for Polymer Research, Waterloo Institute of Nanotechnology, Department of Chemistry, University of Waterloo, Waterloo, ON N2L 3G 1, Canada; E-Mail: jduhamel@uwaterloo.ca Received: 5 December 2011; in revised form: 2 January 2012 / Accepted: 12 January 2012 / Published: 17 January 2012 Abstract: This review exposes the current poor understanding of the internal segmental chain dynamics of dendrimers in solution probed by monitoring the process of excimer formation between pyrene labels covalently attached to the chain ends of dendrimers. The review begins by covering the bases of fluorescence and the kinetics of pyrene excimer formation before describing a procedure based on the Model Free (MF) analysis that is used to analyze quantitatively the fluorescence decays acquired for dendrimers, the ends of which have been fully and covalently labeled with pyrene. Comparison of the various trends obtained by different research groups describing the efficiency of pyrene excimer formation with the generation number of dendrimers illustrates the lack of consensus between the few studies devoted to the topic. One possible reason for this