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persistent luminescence in eu2+-doped compounds a review持续发光奖金再版化合物进行审查.pdf

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persistentluminescenceineu2-dopedcompoundsareview持续发光奖金再版化合物进行审查

Materials 2010, 3, 2536-2566; doi:10.3390/ma3042536 OPEN ACCESS materials ISSN 1996-1944 /journal/materials Review Persistent Luminescence in Eu2+-Doped Compounds: A Review Koen Van den Eeckhout *, Philippe F. Smet and Dirk Poelman Lumilab, Department of Solid State Sciences, Ghent University, Krijgslaan 281S1, 9000 Gent, Belgium; E-Mails: Philippe.Smet@UGent.be (P.F.S.); Dirk.Poelman@UGent.be (D.P.) * Author to whom correspondence should be addressed; E-Mail: Koen.VandenEeckhout@UGent.be; Tel.: +32-9-264-4381; Fax: +32-9-264-4996. Received: 17 January 2001; in revised form: 27 March 2010 / Accepted: 30 March 2010 / Published: 6 April 2010 Abstract: In 1996, Matsuzawa et al. reported on the extremely long-lasting afterglow of SrAl O :Eu2+ codoped with Dy3+ ions, which was more than 10-times brighter than the 2 4 previously widely used ZnS:Cu,Co. Since then, research for stable and efficient persistent phosphors has continuously gained popularity. However, even today - almost 15 years after the discovery of SrAl O :Eu2+, Dy3+ - the number of persistent luminescent materials is 2 4 still relatively low. Furthermore, the mechanism behind this phenomenon is still unclear. Although most authors agree on the general features, such as the existence of long-lived trap levels, many details are still shrouded in mystery. In this review, we present an overview of the important classes of known