preparation of polyester-based metal-cross linked polymeric composites as novel materials resistant to bacterial adhesion and biofilm formation制备polyester-based金属十字架与高分子复合材料是新材料抗细菌粘附和生物膜的形成.pdfVIP

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preparation of polyester-based metal-cross linked polymeric composites as novel materials resistant to bacterial adhesion and biofilm formation制备polyester-based金属十字架与高分子复合材料是新材料抗细菌粘附和生物膜的形成.pdf

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preparation of polyester-based metal-cross linked polymeric composites as novel materials resistant to bacterial adhesion and biofilm formation制备polyester-based金属十字架与高分子复合材料是新材料抗细菌粘附和生物膜的形成

Molecules 2011, 16, 933-950, doi: 10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Preparation of Polyester-Based Metal-Cross Linked Polymeric Composites as Novel Materials Resistant to Bacterial Adhesion and Biofilm Formation Suhair Saleh 1, Bassam Sweileh 2, Sami O. Taha 2, Ruhaifa Mahmoud 3 and Mutasem O. Taha 4,* 1 Department of Pharmaceutical Sciences and Pharmaceutics, Applied Science University, Amman, Jordan 2 Department of Chemistry, Faculty of Sciences, University of Jordan, Amman, Jordan 3 Department of Biology, Faculty of Sciences, University of Jordan, Amman, Jordan 4 Drug Discovery Unit, Department of Pharmaceutical Sciences, Faculty of Pharmacy, University of Jordan, Amman, Jordan * Author to whom correspondence should be addressed; E-Mail: mutasem@.jo; Tel.: +962-777-424750; Fax: +962-653-39649. Received: 27 November 2010; in revised form: 25 December 2010 / Accepted: 17 January 2011 / Published: 21 January 2011 Abstract: Bacterial biofilms constitute an extremely resistant form of bacterial colonization with dire health and economical implications. Towards achieving polymeric composites capable of resisting bacterial adhesion and biofilm formation, we prepared five 2,6-pyridinedicarboxylate-based polyesters employing five different diol monomers. The resulting polyesters were complexed with copper (II) or silver (I). The new polymers were characterized by proton and carbon nuclear magnetic resonance spectroscopy, inherent