preparation of α,β-unsaturated ketones bearing a trifluoromethyl group and their application in organic synthesis制备α,β-unsaturated酮轴承trifluoromethyl集团及其在有机合成中的应用.pdfVIP

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preparation of α,β-unsaturated ketones bearing a trifluoromethyl group and their application in organic synthesis制备α,β-unsaturated酮轴承trifluoromethyl集团及其在有机合成中的应用.pdf

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preparation of α,β-unsaturated ketones bearing a trifluoromethyl group and their application in organic synthesis制备α,β-unsaturated酮轴承trifluoromethyl集团及其在有机合成中的应用

Molecules 1997, 2, 186-232 molecules ISSN 1420-3049 Preparation of ,-Unsaturated Ketones Bearing a Trifluoromethyl Group and Their Application in Organic Synthesis * Valentine G. Nenajdenko , Andrei V. Sanin, Elizabeth S. Balenkova Department of Chemistry, Moscow State University, 119899 Moscow, Russia Tel.: +7 (095) 939-43-94; Fax: +7 (095) 932-88-46; E-mail: Nen@acylium.chem.msu.su Received: 9 December 1996 / Accepted: 28 March 1997 / Published: 1 December 1997 Abstract: The approaches to the synthesis of ,-unsaturated CF -containing ketones and their use in organic 3 chemistry are reviewed. The synthetic applications of these ketones are discussed. The formation of 4-, 5-, 6- and 7-membered heterocycles bearing a CF group based on reactions of ,-unsaturated CF -containing 3 3 ketones with different nucleophiles are discussed. Keywords: ,-Unsaturated trifluoromethyl ketones, CF -containing heterocycles, trifluoroacetylation, 3 synthesis, review. Introduction approaches to the synthesis of CF3-containing heterocycles are based on the use of -dicarbonyl O