random poly(amino acid)s synthesized by ring opening polymerization as additives in the biomimetic mineralization of caco3随机聚(氨基酸)年代由开环聚合合成添加剂仿生矿化的碳酸钙.pdfVIP

Polymers 2012, 4, 1195-1210; doi:10.3390/polym4021195 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Random Poly(Amino Acid)s Synthesized by Ring Opening Polymerization as Additives in the Biomimetic Mineralization of CaCO3 1 2 1 Vladimir Dmitrovic , Gijs J.M. Habraken , Marco M.R.M. Hendrix , Wouter J.E.M. Habraken 1,3, Andreas Heise 2,4, Gijsbertus de With 1 and Nico A.J.M Sommerdijk 1,* 1 Laboratory of Materials and Interface Chemistry and Soft Matter CryoTEM Unit, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, Eindhoven 5600 MB, The Netherlands; E-Mails: v.dmitrovic@tue.nl (V.D.); m.m.r.m.hendrix@tue.nl (M.H.); g.d.with@tue.nl (G.W.); 2 Laboratory of Polymer Chemistry, Eindhoven University of Technology, P.O. Box 513, Eindhoven 5600 MB, The Netherland; E-Mail: gijs.habraken@ (G.H.) 3 Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Am Mühlenberg 1, D-14424 Potsdam, Germany; E-Mail: Wouter.Habraken@mpikg.mpg.de 4 School of Chemical Sciences, Dublin City University, Glasnevin, Dublin 9, Ireland; E-Mail: andreas.heise@dcu.ie * Author to whom correspondence should be addressed; E-Mail: n.sommerdijk@tue.nl; Tel.: +31-402-475-870; Fax: +31-402-445-619. Received: 12 March 2012; in revised form: 8 May 2012 / Accepted: 9 May 2012 / Published: 23 May 2012 Abstract: Biominerals such as bones, teeth and seashells, very often have advanced material properties and are a source of