role of palladium in the redox electrochemistry of ferrocene monocarboxylic acid encapsulated within ormosil networks钯的氧化还原作用电化学二茂铁元羧酸酸性封装在ormosil网络.pdfVIP

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role of palladium in the redox electrochemistry of ferrocene monocarboxylic acid encapsulated within ormosil networks钯的氧化还原作用电化学二茂铁元羧酸酸性封装在ormosil网络.pdf

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role of palladium in the redox electrochemistry of ferrocene monocarboxylic acid encapsulated within ormosil networks钯的氧化还原作用电化学二茂铁元羧酸酸性封装在ormosil网络

Molecules 2005, 10, 728-739 molecules ISSN 1420-3049 Role of Palladium in the Redox Electrochemistry of Ferrocene Monocarboxylic Acid Encapsulated Within ORMOSIL Networks P. C. Pandey* and B. C. Upadhyay Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi-221 005, India. Tel. (+91)-542-2317745, Fax (+91) 542-2368174, * Author to whom correspondence should be addressed; e-mail pcpandey@bhu.ac.in and pandey_pc@ Received: 29 November 2004 / Accepted: 14 January 2005 / Published: 14 July 2005 Abstract: We report herein the effect of palladium on the redox electrochemistry of ferrocene monocarboxylic acid encapsulated within an organically modified sol-gel glass network (ORMOSIL). It has been found that amount of palladium and its geometrical distribution significantly alter the redox electrochemistry of FcMCA. The geometrical distribution of palladium has been controlled by two methods: (i) palladium is allowed to link within nanostructured network of the ORMOSIL which was subsequently availed from the reactivity of palladium chloride and trimethoxysilane; (ii) palladium powder is encapsulated together FcMCA thus allowing the presence of palladium within the nanoporous domain. The content of palladium is varied by controlling the reaction dynamics of palladium chloride and trimethoxysilane interaction. For this we initially allowed to trigger hydrolysis, condensatio