screening analyses of pinosylvin stilbenes, resin acids and lignans in norwegian conifers筛选分析pinosylvin对称二苯代乙烯、树脂酸和木酚素在挪威松柏.pdfVIP

Molecules 2006, 11, 103-114 molecules ISSN 1420-3049 Screening Analyses of Pinosylvin Stilbenes, Resin Acids and Lignans in Norwegian Conifers Hanne Hovelstad 1, Ingebjorg Leirset 1, Karin Oyaas 1,† and Anne Fiksdahl 2,* 1 Paper and Fibre Institute (PFI), Høgskoleringen 6B, NO-7491 Trondheim, Norway. 2 Department of Chemistry, Norwegian University of Science and Technology, NTNU, NO-7491 Trondheim, Norway. † Current address: Gaia Lab AS, NO-7228 Kvaal, Norway. * Author to whom correspondence should be addressed; E-mail: Anne.Fiksdahl@chem.ntnu.no Received: 6 January 2006; in revised form: 23 January / Accepted: 24 January 2006 / Published: 31 January 2006 Abstract: The content and distribution of stilbenes and resin acids in Scots pine (Pinus sylvestris) and spruce (Picea abies), sampled in central Norway, have been examined. The contents of pinosylvin stilbenes in pine heartwood/living knots were 0.2-2/2-8 % (w/w). No stilbenes could be detected in spruce (Picea abies). The resin acid contents of pine sapwood/heartwood and knots were 1-4 and 5-10 % (w/w), respectively. Minor amounts of resin acids (0.2/0.04 %w/w) were identified in spruce wood/knots. The lignan content in knots of Norwegian spruce was 6.5 % (w/w). Diastereomerically pure hydroxymatairesinol (HMR, 84 % of total lignans) was readily isolated from this source since only minor quantities (2.6 % of total lignans) of the allo-HMR diastereomer was detected. Insignificant amounts of lignans were present in the sapwood. Lignans