超重力_水热法制备绿色纳米阻燃材料.pdfVIP

2006 25 2 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·181 · - 100029 350 51 pH 2040 nm100200 nm50100 nm + TQ 050.4 21 A 1000 6613 2006 02 0181 06 Preparation of green nano flame retardant by high gravity-thermal hydrolysis WANG DongguangGUO FenCHEN JianfengZHANG Zeting Key Lab for Nanomaterials Ministry of Education Research Center of the Ministry of Education for High Gravity Engineering and Technology Beijing University of Chemical Technology Beijing 100029 Abstract Nano aluminum trihydroxide gels were prepared by carbonation in rotating packed bed under high gravity then were subsequently modified by thermal hydrolysis in an agitated closed vessel to synthesize a novel nano-scale modified aluminum hydroxide powder with the beginning of thermal decomposition higher than 350 and weight loss of 51%. The mechanisms of carbonation and modification processes, as well as the influences of such factors as temperature, high gravity level, gas/liquid ratio, sodium aluminate concentration, final pH on carbonation and the influences of such factors as selection of precursors, temperature, modifier/ aluminum trihydroxide, aluminum trihydroxide concentration on modification were analyzed in detail. The modified product was formed by esterification and had ultra thin rhombic morphology of 2040 nm in thi