simultaneous patterning of independent metalmetal oxide multi-layer films using two-tone photo-acid generating compound systems深浅不一的同步模式的独立metalmetal氧化物多层电影使用photo-acid生成复合系统.pdfVIP
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simultaneous patterning of independent metalmetal oxide multi-layer films using two-tone photo-acid generating compound systems深浅不一的同步模式的独立metalmetal氧化物多层电影使用photo-acid生成复合系统
Nanomaterials 2012, 2, 312-328; doi:10.3390/nano2040312
OPEN ACCESS
nanomaterials
ISSN 2079-4991
/journal/nanomaterials
Article
Simultaneous Patterning of Independent Metal/Metal Oxide
Multi-Layer Films Using Two-Tone Photo-Acid Generating
Compound Systems
Christopher E. J. Cordonier * and Hideo Honma
Materials Surface Engineering Research Institute, Kanto Gakuin University, 1-1-1 Fukuura,
Kanazawa, Yokohama 236-8501, Japan; E-Mail: honma@kanto-gakuin.ac.jp
* Author to whom correspondence should be addressed; E-Mail: chris@kanto-gakuin.ac.jp;
Tel.: +81-45-353-9747; Fax: +81-45-370-7132.
Received: 29 June 2012; in revised form: 20 September 2012 / Accepted: 24 September 2012 /
Published: 16 October 2012
Abstract: (1) The photo-induced solubility and positive-tone direct photo-patterning
of iron, copper and lanthanides chelated with 4-(2-nitrobenzyloxycarbonyl)catechol
(NBOC) or 4-(6-nitroveratryloxycarbonyl)catechol (NVOC) was investigated.
Photo-patterning of iron, copper, cerium, samarium, europium, terbium, dysprosium,
holmium, erbium and lutetium complexes was accomplished. Continuous films were
formed by the pyrolysis of metal complex films at 500 °C. (2) Based on the difference in
the photo-reaction excitation wavelength profile of NBOC and NVOC complexes, a short
and simple method for simultaneous micro-patterning of two independent films on each
side of a transparent glass substrate was developed. Using the developed procedure, ind
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