原创力文档spectroscopy and 1μm luminescence by visible quantum cutting in pr3+-yb3+ codoped glass由可见光谱和1μm发光量子切割pr3 + -yb3 + codoped玻璃.pdfVIP
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spectroscopyand1μmluminescencebyvisiblequantumcuttinginpr3-yb3codopedglass由可见光谱和1μm发光量子切割pr3-yb3codoped玻璃
Materials 2010, 3, 2405-2411; doi:10.3390/ma3042405
OPEN ACCESS
materials
ISSN 1996-1944
/journal/materials
Article
Spectroscopy and 1m Luminescence by Visible Quantum
Cutting in Pr3+-Yb3+ Codoped Glass
Yumiko Katayama * and Setsuhisa Tanabe
Graduate School of Human and Environmental Studies, Kyoto university / Yoshida-nihonmatsu-cho,
Sakyo-ku, Kyoto 606-8501, Japan; E-Mail: stanabe@gls.mbox.media.kyoto-u.ac.jp (S.T.)
* Author to whom correspondence should be addressed;
E-Mail: yumiko@h05ktym.mbox.media.kyoto-u.ac.jp; Tel.: +81-75-753-6817;
Fax: +81-75-753-6694.
Received: 28 December 2009; in revised form: 25 January 2010 / Accepted: 25 March 2010 /
Published: 29 March 2010
Abstract: The quantum cutting phenomenon of a blue photon into two infrared photons is
reported in glass codoped with Pr3+-Yb3+ ions. Oxyfluoride glass with compositions of
32SrF -0.1PrF -2.9YbF -42SiO -23Al O were prepared, and photoluminescence
2 3 3 2 2 3
properties in the range from visible to near-infrared were investigated. Evidence of several
3+ 3 1 3+ 2 2 3+ 1 3
energy transfers, such as (Pr : P →G )→(Yb : F ←F ) and (Pr : D →F ,
0 4 5/2 7/2 2 4
3 3+ 2 2 3+ 3+
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