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surface science studies of gas sensing materials sno2表面科学研究sno2的气体传感材料
Sensors 2006, 6, 1345-1366
sensors
ISSN 1424-8220
© 2006 by MDPI
/sensors
Review
Surface Science Studies of Gas Sensing Materials: SnO2
Matthias Batzill
Department of Physics, University of South Florida, Tampa, FL 33620, USA
E-mail: mbatzill@
Received: 26 September 2006 / Accepted: 16 October 2006 / Published: 17 October 2006
Abstract: This review is an attempt to give an overview on how surface science studies can
contribute to a fundamental understanding of metal oxide gas sensors. In here tin dioxide is
used as a model system for metal oxide gas sensor materials and we review surface science
studies of single crystal SnO2. The composition, structure, electronic and chemical
properties of the (110) and (101) surfaces is described. The influence of compositional
changes as a function of the oxygen chemical potential on the electronic surface structure
and the chemical properties is emphasized on the example of the (101) surface. The surface
chemical properties are discussed on the example of water adsorption. It is shown the
chemical and gas sensing properties depend strongly on the surface composition.
Keywords: surface science, single crystal, metal oxide surfaces, photoemission, scanning
tunneling microscopy.
1. Introduction
Metal oxides, such as ZnO, In O , SnO , etc., have been studied extensively for their gas response
2 3 2
to oxidizing and reducing gases
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