原创力文档synthesis and characterization of a ru(ii) complex with functionalized phenanthroline ligands having single-double linked anthracenyl and 1-methoxy-1-buten-3-yne moieties俄文(ii)的合成和表征复杂的功能化菲罗啉配体有单键双键anthracenyl和1-methoxy-1-buten-3-yne根有关.pdfVIP
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synthesis and characterization of a ru(ii) complex with functionalized phenanthroline ligands having single-double linked anthracenyl and 1-methoxy-1-buten-3-yne moieties俄文(ii)的合成和表征复杂的功能化菲罗啉配体有单键双键anthracenyl和1-methoxy-1-buten-3-yne根有关
Molecules 2010, 15, 7570-7581; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Synthesis and Characterization of a Ru(II) Complex with
Functionalized Phenanthroline Ligands Having Single-Double
Linked Anthracenyl and 1-Methoxy-1-buten-3-yne Moieties
Adewale O. Adeloye and Peter A. Ajibade *
Department of Chemistry, Faculty of Science and Agriculture, University of Fort Hare, Private Bag
X1314, Alice 5700, South Africa
* Author to whom correspondence should be addressed; E-Mail: pajibade@ufh.ac.za;
Tel.: +27-406-022-055; Fax: +27-406-022-094.
Received: 8 September 2010 / Accepted: 19 October 2010 / Published: 27 October 2010
Abstract: Two series of bidentate polypyridine ligands, made of phenanthroline chelating
subunits having substituted mono-and di-anthracenyl groups, and 1-methoxy-1-buten-3-
yne at the 4 and 7-positions with the corresponding heteroleptic Ru(II) complex have been
synthesized and characterized. The complex is formulated as [(Ru(L )(L )(NCS) )],
1 2 2
(where L1 = 4-(9-dianthracenyl-10-(2,3-dimethylacrylic acid)-7-(9-anthracenyl-10-(2,3-
dimethylacrylic acid)-1,10-phenanthroline and L2 = 4,7-bis(1-methoxy-1-buten-3-yne)-
1,10-phenanthroline). The Ru(II) complex shows characteristic broad and intense metal-to-
ligand charge transfer (MLCT) bands absorption and appreciable photoluminescence
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