synthesis and characterization of novel inorganic-organic hybrid ru(ii) complexes and their application in selective hydrogenation合成和表征的新型无机混合俄文(ii)配合物在选择性加氢和他们的应用程序.pdfVIP

Molecules 2010, 15, 1028-1040; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Synthesis and Characterization of Novel Inorganic-Organic Hybrid Ru(II) Complexes and Their Application in Selective Hydrogenation Ismail Warad 1,*, Zeid Al-Othman 1, Saud Al-Resayes 1, Salem S. Al-Deyab 2 and El-Refaie 2 Kenawy 1 Department of Chemistry, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia 2 Petrochemical Research Chair, Department of Chemistry, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia  Author to whom correspondence should be addressed; E-Mail: warad@.sa; Tel./Fax: +96-61-4675992. Received: 31 December 2009; in revised form: 21 January 2010 / Accepted: 18 February 2010 / Published: 23 February 2010 Abstract: Novel Ru(II) complex-based hybrid inorganic-organic materials immobilized via a diamine co-ligand site instead of the conventional diphosphine ligand have been prepared. The complexes were prepared by two different methods: sol-gel and surface modification techniques. The structures of the desired materials were deduced by several 1 13 available physical measurements like elemental analyses, infrared, FAB-MS and H-, C- and 31P-NMR spectroscopy. Due to a lack of solubility the structures of xerogel 3 and modified 4 were studie