原创力文档sunflower-based feedstocks in nonfood applications perspectives from olefin metathesis从烯烃复分解sunflower-based原料在非食品应用中观点.pdfVIP
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sunflower-based feedstocks in nonfood applications perspectives from olefin metathesis从烯烃复分解sunflower-based原料在非食品应用中观点
Int. J. Mol. Sci. 2008, 9, 1393-1406; DOI: 10.3390/ijms9081393
OPEN ACCESS
International Journal of
Molecular Sciences
ISSN 1422-0067
/ijms/
Review
Sunflower-based Feedstocks in Nonfood Applications:
Perspectives from Olefin Metathesis
Bassie B. Marvey
Department of Chemistry, North-West University, P/Bag X2046, Mafikeng, 2735, South Africa.
Tel. +27-18-389-2527; Fax: +27-18-389-2052; E-Mail: bassie.marvey@nwu.ac.za
Received: 4 Jun 2008; in revised form: 29 July 2008 / Accepted: 30 July 2008 / Published: 13 August
2008
Abstract: Sunflower (Helianthus annuus L .) oil remains under-utilised albeit one of the
major seed oils produced world-wide. Moreover, the high oleic sunflower varieties make
the oil attractive for applications requiring high temperature processes and those targeting
the C=C double bond functionality. Herein an overview of the recent developments in
olefin metathesis of sunflower-based feedstocks is presented. The improved performance
of olefin metathesis catalysts leading to high turnover numbers, high selectivity and
catalyst recyclability, opens new opportunities for tailoring sunflower-based feedstocks
into products required for possible new niche market applications. Promising results in
biofuel, biopolymers, fragrances and fine chemicals applications have been reported.
Keywords: sunflower, nonfood applications, olefin metathesis.
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