原创力文档synthesis and characterization of polyacetylene with side-chain thiophene functionality合成和表征与侧链的聚乙炔噻吩的功能.pdfVIP
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synthesis and characterization of polyacetylene with side-chain thiophene functionality合成和表征与侧链的聚乙炔噻吩的功能
Int. J. Mol. Sci. 2008, 9, 383-393
International Journal of
Molecular Sciences
ISSN 1422-0067
© 2008 by MDPI
/ijms/
Full Research Paper
Synthesis and Characterization of Polyacetylene with Side-chain
Thiophene Functionality
Banu Koz, Baris Kiskan and Yusuf Yagci *
Istanbul Technical University, Department of Chemistry, Maslak 34469, Istanbul, Turkey
Tel. +90 212 285 6325 or 3241; Fax: +90 212 285 6169 or 6386; E-mails: banukoz@.tr;
kiskanb@.tr; yusuf@.tr
* Author to whom correspondence should be addressed.
Received: 30 November 2007; in revised form: 30 January 2008 / Accepted: 29 February 2008 /
Published: 18 March 2008
Abstract: A new polyacetylene derivative with electroactive thiophene substituent, namely
poly(2-methylbut-2-enyl thiophene-3-carboxylate) was synthesized and characterized. For
this purpose, novel acetylene monomer was synthesized by the reaction of 3-
thiophenecarboxylic acid with propargyl bromide and polymerized with a Rh catalyst to
give the corresponding polymer. The chemical structure of the polymer was characterized
to comprise the conjugated backbone and electroactive thiophene side group. UV spectral
changes of the polymer with temperature were also studied. The polymer exhibited better
thermal stability than the unsubstituted polyacetylenes.
Keywords: Polyacetylene, Helical polymer, Conjugated polymer, Thiophene.
Introduction
It is known that sub
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