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synthesis of polymer—mesoporous silica nanocompositespolymer-mesoporous二氧化硅纳米复合材料的合成.pdf

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synthesis of polymer—mesoporous silica nanocompositespolymer-mesoporous二氧化硅纳米复合材料的合成

Materials 2010, 3, 4066-4079; doi:10.3390/ma3074066 OPEN ACCESS materials ISSN 1996-1944 /journal/materials Review Synthesis of Polymer—Mesoporous Silica Nanocomposites Liangming Wei, Nantao Hu and Yafei Zhang * National Key Laboratory of Nano/Micro Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of Ministry of Education, Institute of Micro and Nano Science and Technology, Shanghai Jiao Tong University, Dongchuan Road, Shanghai, 200240, China; E-Mails: hunantao@(N.T.H.); lmwei@(L.M.W.) * Author to whom correspondence should be addressed; E-Mail: yfzhang@. Received: 13 June 2010 / Accepted: 6 July 2010 /Published: 13 July 2010 Abstract: Polymer nanocomposites show unique properties combining the advantages of the inorganic nanofillers and the organic polymers. The mesoporous silica nanofillers have received much attention due to their ordered structure, high surface area and ease for functionalization of the nanopores. To accommodate macromolecules, the nanopores lead to unusually intimate interactions between the polymer and the inorganic phase, and some unusual properties can be observed, when compared with nonporous fillers. Whereas many review articles have been devoted to polymer/nonporous nanofiller nanocomposites, few review articles focus on polymer/mesoporous silica nanocomposites. This review summarizes the recent development in the methods for synthesizing polymer/mesoporous silica nanocomposites based on the papers publ