原创力文档- 1、本文档共8页，可阅读全部内容。
- 2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
- 3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
- 5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
- 6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
- 7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
- 8、VIP文档为合作方或网友上传，每下载1次， 网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档
查看更多
synthesis of symmetrical and non-symmetrical diimines from dimedone从双甲酮合成的对称和不对称二亚胺
Molecules 2009, 14, 2278-2285; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Synthesis of Symmetrical and Non-symmetrical Diimines from
Dimedone
Bahjat A. Saeed * and Ibrahim A. Musad
University of Basrah, College of Education, Chemistry Department, Basrah, Iraq
* Author to whom correspondence should be addressed; E-mail: bas_chem_dep@
Received: 7 May 2009; in revised form: 21 May 2009 / Accepted: 9 June 2009 /
Published: 24 June 2009
Abstract: Symmetrical and non-symmetrical diimines derived from dimedone were
synthesized by the reaction of their corresponding enaminothiones with primary amines.
The synthesized compounds were characterized using micro analytical data and NMR
spectroscopy. Theoretical calculations by B3LYP/6-31G(d,p) level of theory show that the
enolic form is the most stable within the possible tautomeric forms of the compounds.
Keywords: dimedone; diimines; enaminothiones; B3LYP/6-31G(d,p)
Introduction
Diimines of β-diketones have received significantly increasing attention which stems from the
scope for variation of the substituents on the nitrogen atoms [1]. In addition, they have been used as
precursors to some heterocyclic compounds such as imidazolines, pyrimidines and carbapenem
intermediates [2,3]. There are two synthetic procedures for the conversion of β-diketone into a β-
diketimine [1]. The first is to convert the diketone to the dioxyalkanone, which is t
您可能关注的文档
- svmtrip a method to predict antigenic epitopes using support vector machine to integrate tri-peptide similarity and propensitysvmtrip方法预测抗原决定使用支持向量机集成tri-peptide相似性和倾向.pdf
- syk-mediated translocation of pi3kδ to the leading edge controls lamellipodium formation and migration of leukocytessyk-mediated易位的pi3kδ前缘控制lamellipodium形成和白细胞的迁移.pdf
- symbiodinium—invertebrate symbioses and the role of？metabolomicssymbiodinium-invertebrate共生,和的作用代谢组学.pdf
- symmetric matrix fields in the finite element method在有限元方法中对称矩阵字段.pdf
- symbiotic legume nodules employ both rhizobial exo- and endo-hydrogenases to recycle hydrogen produced by nitrogen fixation共生豆类结节雇佣两个rhizobial外和endo-hydrogenases回收氢由固氮.pdf
- symmetrically and unsymmetrically bridged methylenebis(allopurinols) synthesis of dimeric potential anti-gout drugs对称和偏压地段桥梁制(别嘌呤醇)的合成二聚的潜在anti-gout药物.pdf
- switchable thermal interfaces based on discrete liquid droplets可切换的基于离散液滴的热接口.pdf
- symmetries of spatial graphs and rational twists along spheres and tori空间图形的对称性和理性曲折球体和花床.pdf
- symmetries of the central vestibular system forming movements for gravity and a three-dimensional world对称中枢前庭系统形成运动的重力和一个三维的世界.pdf
- symmetry analysis in mechanistic studies of nucleophilic substitution and β-elimination reactions对称性分析在机械的亲核取代和β-elimination反应的研究.pdf
- synthesis of some transition metal complexes of a novel schiff base ligand derived from 2,2'-bis(p-methoxyphenylamine) and salicylicaldehyde一些过渡金属配合物的合成一种新型席夫碱配体来源于2,2u2019bis(p-methoxyphenylamine)和salicylicaldehyde.pdf
- synthesis of the key intermediate of coenzyme q10关键中间体的合成辅酶q10.pdf
- synthesis of the key precursor of hirsutellide a合成前体的hirsutellide的关键.pdf
- synthesis of the marine pyrroloiminoquinone alkaloids, discorhabdins海洋pyrroloiminoquinone生物碱的合成,discorhabdins.pdf
- synthesis of the marine bromotyrosine psammaplin f and crystal structure of a psammaplin a analogue合成海洋bromotyrosine psammaplin psammaplin f和晶体结构的模拟.pdf
- synthesis of the system modeling and signal detecting circuit of a novel vacuum microelectronic accelerometer合成系统的建模和信号检测电路的一种新型真空微电子加速度计.pdf
- synthesis of thiadiazoles and 1,2,4-triazoles derived from cyclopropane dicarboxylic acid合成thiadiazoles和1、2、4-triazoles来自环丙烷二羧酸.pdf
- synthesis of tetrasubstituted alkenes via metathesis通过交换tetrasubstituted烯烃的合成.pdf
- synthesis of triptorelin lactate catalyzed by lipase in organic media由脂肪酶在有机催化合成乳酸曲普瑞林的媒体.pdf
- synthesis of two new hemisynthetic diterpenylhydroquinones from natural ent-labdanes合成两个新的hemisynthetic diterpenylhydroquinones自然ent-labdanes.pdf
文档评论（0）