synthesis of some transition metal complexes of a novel schiff base ligand derived from 2,2-bis(p-methoxyphenylamine) and salicylicaldehyde一些过渡金属配合物的合成一种新型席夫碱配体来源于2,2u2019bis(p-methoxyphenylamine)和salicylicaldehyde.pdfVIP

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synthesis of some transition metal complexes of a novel schiff base ligand derived from 2,2-bis(p-methoxyphenylamine) and salicylicaldehyde一些过渡金属配合物的合成一种新型席夫碱配体来源于2,2u2019bis(p-methoxyphenylamine)和salicylicaldehyde.pdf

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synthesis of some transition metal complexes of a novel schiff base ligand derived from 2,2-bis(p-methoxyphenylamine) and salicylicaldehyde一些过渡金属配合物的合成一种新型席夫碱配体来源于2,2u2019bis(p-methoxyphenylamine)和salicylicaldehyde

Molecules 2003, 8, 439-443 molecules ISSN 1420-3049 Synthesis of Some Transition Metal Complexes of a Novel Schiff Base Ligand Derived from 2,2-bis(p -Methoxyphenylamine) and Salicylicaldehyde Xishi Tai 1,*, Xianhong Yin 1,2, Qiang Chen 1 and Minyu Tan 1 1 College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, P. R.China. 2 Chemistry Department, Guangxi University for Nationalities, Nanning, 530006, P. R. China. * Author to whom correspondence should be addressed; e-mail: taixishi@ Received: 25 February 2003; in revised form: 3 April 2003 / Accepted: 5 April 2003 / Published: 31 May 2003 Abstract: A novel Schiff base ligand derived from 2,2-bis(p -methoxyphenylamine) and salicylicaldehyde and its transition metal complexes with Cu ( Ⅱ), Co ( Ⅱ) and Mn ( Ⅱ) have been synthesized. Their spectral properties and electrochemical behavior were investigated. Keywords: Schiff base; transition metal complexes; synthesis; properties. Introduction During the past two decades, considerable attention has been paid to the chemistry of the metal complexes of Schiff bases containing nitrogen and other donors [1-4]. This may be attributed to their stability, biological activity [5] and potential applications in many fields such as oxidation catalysis [6], electrochemistry [7], etc. Herein we report the synthesis of a novel Schiff base ligand (H2L) and its Cu (II), Co (II) and Mn (II) complexes. Their spectral properties and electrochemical behavior were investigated. Molecules 2003, 8