synthesis, binding and fluorescence studies of bis-2-amidopyrrole receptors for bis-carboxylate anions合成、绑定和荧光的研究bis-2-amidopyrrole bis-carboxylate阴离子受体.pdfVIP

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synthesis, binding and fluorescence studies of bis-2-amidopyrrole receptors for bis-carboxylate anions合成、绑定和荧光的研究bis-2-amidopyrrole bis-carboxylate阴离子受体.pdf

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synthesis, binding and fluorescence studies of bis-2-amidopyrrole receptors for bis-carboxylate anions合成、绑定和荧光的研究bis-2-amidopyrrole bis-carboxylate阴离子受体

Sensors 2009, 9, 1534-1540; doi:10.3390/ OPEN ACCESS sensors ISSN 1424-8220 /journal/sensors Communication Synthesis, Binding and Fluorescence Studies of Bis-2-amidopyrrole Receptors for Bis-carboxylate Anions Belén Jiménez 1, Emilio Calle 2 and Cruz Caballero 1,* 1 Organic Chemistry Department, Plaza de los Caidos, 1-5, University of Salamanca, E-37008 Salamanca, Spain; E-Mail: belenjj@yahoo.es 2 Physical Chemistry Department. Plaza de los Caidos 1-5, University of Salamanca, E-37008 Salamanca, Spain; E-Mail: ecalle@usal.es * Author to whom correspondence should be addressed; E-Mail: ccsa@usal.es; Tel.: +34-923-294481 Received: 12 February 2009; in revised form: 27 February 2009 / Accepted: 2 March 2009 / Published: 4 March 2009 Abstract: The ditopic neutral receptors 1 and 2 were synthesized for the recognition and sensing of bis-carboxylates. They are based on pyrrole and amide groups as hydrogen-bond donors to bind the oxoanions of the guests. Among the obtained results, the selectivity for glutarate over succinate is particularly interesting. Compound 1 behaves as a PET fluorescence sensor for glutarate. Keywords: Molecular recognition, bis-2-amidopyrrole receptors, bis-carboxylate anions, fluorescent sensor; hydrogen bonding. 1. Introduction The selective recognition and sensing of anions by synthetic host molecules has become an important area of interest and activity in molecular recognition [1]. Among them, owing to their chemical and biolo