the effect of the argon carrier gas in the multiphoton dissociation-ionization of tetracene氩载气的效果的多光子dissociation-ionization并四苯.pdfVIP
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the effect of the argon carrier gas in the multiphoton dissociation-ionization of tetracene氩载气的效果的多光子dissociation-ionization并四苯
Int. J. Mol. Sci. 2008, 9, 2003-2015; DOI: 10.3390/ijms9102003
OPEN ACCESS
International Journal of
Molecular Sciences
ISSN 1422-0067
/ijms
Article
The Effect of the Argon Carrier Gas in the Multiphoton
Dissociation-Ionization of Tetracene
*
Juan Carlos Poveda , Alejandro San Román, Alfonso Guerrero, Ignacio Álvarez and Carmen
Cisneros
Laboratorio de Colisiones Atómicas Moleculares, Instituto de Ciencias Físicas, Universidad Nacional
Autónoma de México, Av. Universidad Colonia Chamilpa, Cuernavaca, Morelos C.P. 62210, México.
E-Mails: asanroman@fis.unam.mx (A. R.); alfonsog@fis.unam.mx (A. G.);
ialvarez@fis.unam.mx (I. Á.); carmen@fis.unam.mx (C. C.)
* Author to whom correspondence should be addressed; E-Mail: jkclimb@fis.unam.mx;
Tel. +57-777-3172588
Received: 12 August 2008; in revised form: 10 October 2008 / Accepted: 15 October 2008 /
Published: 28 October 2008
Abstract: The multiphoton dissociation-ionization of tetracene at 355 nm using 6.5
nanosecond laser pulses, with and without argon as a carrier gas (CG), has been studied
and compared. Ion fragments were analyzed in a time-of-flight mass spectrometer and
separated according to their mass-to-charge ratio (m/z). The results show that the dynamic
of photodissociation at ~1010 W⋅cm-2 intensities is strongly influenced by the CG. The
suppression of fragmentation channels primarily those relatin
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