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voltammetric behavior of o-nitrophenol and damage to dnao-nitrophenol伏安行为和损伤dna
Int. J. Mol. Sci. 2008, 9, 316-326
International Journal of
Molecular Sciences
ISSN 1422-0067
© 2008 by MDPI
/ijms/
Full Research Paper
Voltammetric Behavior of o-Nitrophenol and Damage to DNA
*
Da-Peng Zhang, Wei-Li Wu, Hai-Yan Long, Yun-Chun Liu and Zhou-Sheng Yang
College of Chemistry and Materials Science, Anhui Key Laboratory of Chemo-Biosensing, Anhui
Normal University, Wuhu 241000, P.R. China
* Author to whom correspondence should be addressed; E-mail: yzhoushe@;
Tel. +86-553-3869303
Received: 3 December 2007; in revised form: 15 February 2008 / Accepted: 29 February 2008 /
Published: 12 March 2008
Abstract: The electrochemical behavior of o-nitrophenol was studied in detail with a
glassy carbon electrode (GCE). The dependence of peak potential on pH indicated that
equivalent electrons and protons were involved in the process of o-nitrophenol reduction.
The interaction of o-nitrophenol with calf thymus DNA was investigated by adding DNA
to the o-nitrophenol solution and by immobilizing DNA on GCE, respectively. The peak
current decrement and peak potential shift in presence of DNA indicated that o-nitrophenol
could interact with DNA. The result was demonstrated that the in situ DNA damage was
detected by differential pulse voltammetry after the o-nitrophenol was electroch
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