hank忆s溶液中注碳ti6al4v合金缝隙试样的电化学行为.pdf

第20卷摇 第5期 材摇 料摇 科摇 学摇 与摇 工摇 艺 Vol.20 No.5 摇 摇 20 12年10月 MATERIALS SCIENCE TECHNOLOGY Oct. ,2012 摇 摇 摇 摇 摇 摇 Hank忆s溶液中注碳 Ti6Al4V合金缝隙 试样的电化学行为 杨摇 慧,梁成浩,黄乃宝 (大连海事大学 交通运输装备与海洋工程学院,大连 116026) 摘摇 要:为探索碳离子注入Ti-6Al-4V合金在人工模拟体液Hank忆s溶液中的性能,采用电化学方法、扫描 电子显微镜和X射线衍射对其缝隙试样在人工模拟体液Hank忆s 溶液中的电化学行为进行了研究.结果表 明:碳离子注入后,Ti-6Al-4V合金缝隙试样的腐蚀电位升高、电荷转移电阻增大,阳极极极化电流密度降 低,改善了电化学性能;碳离子注入后,Ti-6Al-4V合金表面形成主要由TiC组成的无序层膜,该膜层阻滞 了合金元素的溶解,提高了合金的耐缝隙腐蚀性能. 关键词:碳离子注入;Ti-6Al-4V合金;Hank忆s人工模拟体液;缝隙腐蚀行为 中图分类号:TG172.3 文献标志码:A 文章编号:1005-0299(2012)05-0021-05 Electrochemical behavior of crevice samples of Ti6Al4V alloy implanted carbon ion in Hank忆s solution YANG Hui,LIANG Cheng鄄hao,HUANG Nai鄄bao (Transportation Equipments and Ocean Engineering College,Dalian Maritime University,Dalian 116026,China) Abstract:To explore the characteristic of Ti -6Al -4V alloy implanted carbon iontion in Hanks simulated body fluid solution,the electrochemical behavior of crevice samples was studied by electrochemical method in Hank爷s artificial body fluids.The results showed that the corrosion potential of implanted samples moved to鄄 ward positive,thechargetransferresistanceturnedtobig,andtheanodicpolarizedcurrentdensitywasreduced during crevice corrosion,which resulted in improving its electrochemical characteristic.The reason lied in the unorderedfilmformedonthe surfaceofTi-6Al-4V alloy,whichwasmainly composedofTiCafter implanta鄄 tion.The unordered film blocked alloy element to dissolve and improved alloy忆s crevice corrosion resistance. Key words:carbon ion implantation;Ti -6Al -4V alloy;Hank忆s art